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Abstract | Cited by

The CuAAC active-template approach was exploited to construct rotaxanes incorporating cage-like silsesquioxane stoppers, namely, POSSaxanes. The compounds were characterized in the solution and solid state, providing the unprecedented molecular structures of POSS-incorporating rotaxanes.

Graphical abstract: POSSaxanes: active-template synthesis of organic–inorganic rotaxanes incorporating cubic silsesquioxane stoppers

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