Issue 46, 2023
From the journal:

Chemical Communications

Ruthenium-catalysed N-alkylation of anilines with primary carbohydrate alcohols via borrowing hydrogen strategy†

Kouki Tsuge,a   Shunnichi Kubota,a   Kana Sakamoto,a   Kenji Kitayamab  and  Takahiro Nishimura ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Osaka Metropolitan University, Sumiyoshi, Osaka 558-8585, Japan
E-mail: tnishi@omu.ac.jp

b Daicel Corporation, Grand Front Osaka Tower-B, 3-1, Ofuka-cho, Kita-ku, Osaka 530-0011, Japan

Abstract

Ruthenium-catalysed N-alkylation of anilines with sugar derivatives proceeded via the borrowing hydrogen strategy. Primary carbohydrate alcohols were successfully applied to N-alkylation of aniline derivatives to give the corresponding aminosugars in high yields.

Graphical abstract: Ruthenium-catalysed N-alkylation of anilines with primary carbohydrate alcohols via borrowing hydrogen strategy

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Article information

DOI
https://doi.org/10.1039/D3CC01931D
Article type
Communication
Submitted
20 Apr 2023
Accepted
16 May 2023
First published
17 May 2023
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2023,59, 7052-7055

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Ruthenium-catalysed N-alkylation of anilines with primary carbohydrate alcohols via borrowing hydrogen strategy

K. Tsuge, S. Kubota, K. Sakamoto, K. Kitayama and T. Nishimura, Chem. Commun., 2023, 59, 7052 DOI: 10.1039/D3CC01931D

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