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A self-supported NiTeO3 perovskite is made by deploying an extended hydrothermal tellurization strategy with a restricted Te content, which was found to be exceptionally active towards the oxidation of water and methanol and the reduction of water in 1.0 M KOH where it delivered −10 mA cm−2 at just −1.54 V for a full cell featuring MOR‖HER.

Graphical abstract: A tri-functional self-supported electrocatalyst featuring mostly NiTeO3 perovskite for H2 production via methanol–water co-electrolysis

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