Issue 84, 2023

Non-covalent matere bonds in perrhenates probed via ultrahigh field rhenium-185/187 NMR and zero-field NQR spectroscopy

Abstract

Matere bonds (MaB) to rhenium in a set of organic perrhenates are probed via185/187Re solid-state NMR in applied magnetic fields of up to 35.2 T, and via185/187Re NQR. 185/187Re quadrupolar couplings distinguish between MaB samples and control samples, and their precise values are governed by shear strain of the ReO4 anions.

Graphical abstract: Non-covalent matere bonds in perrhenates probed via ultrahigh field rhenium-185/187 NMR and zero-field NQR spectroscopy

Supplementary files

Article information

Article type
Communication
Submitted
23 Aug 2023
Accepted
21 Sep 2023
First published
21 Sep 2023

Chem. Commun., 2023,59, 12609-12612

Author version available

Non-covalent matere bonds in perrhenates probed via ultrahigh field rhenium-185/187 NMR and zero-field NQR spectroscopy

Y. Xu, M. Calabrese, N. Demitri, A. Pizzi, T. Nag, I. Hung, Z. Gan, G. Resnati and D. L. Bryce, Chem. Commun., 2023, 59, 12609 DOI: 10.1039/D3CC04090A

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