Water vapour induced structural flexibility in a square lattice coordination network†
Kyriaki
Koupepidou, 
a
Andrey A.
Bezrukov,
a
Dominic C.
Castell,
a
Debobroto
Sensharma,
a
Soumya
Mukherjee
a
and
Michael J.
Zaworotko
*a
a
Andrey A.
Bezrukov,
a
Dominic C.
Castell,
a
Debobroto
Sensharma,
a
Soumya
Mukherjee
a
and
Michael J.
Zaworotko
*a
Abstract
Herein, we introduce a new square lattice topology coordination network, sql-(1,3-bib)(ndc)-Ni, with three types of connection and detail its gas and vapour induced phase transformations. Exposure to humidity resulted in an S-shaped isotherm profile, suggesting potential utility of such materials as desiccants.
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