Issue 95, 2023
From the journal:

Chemical Communications

Double-stranded metallo-triangles: from anion-templated nonanuclear to cation-templated tetraicosanuclear dysprosium clusters†

Yanan Liu,‡a   Xiao Sun,‡a   Peiqiong Chen,a   Xiaojuan Li,a   Fu-Ping Huang, ORCID logo *b   Hou-Ting Liu*a  and  Haiquan Tian ORCID logo *a  

* Corresponding authors

a Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, P. R. China
E-mail: tianhaiquan2019@163.com, liuhouting@lcu.edu.cn

b Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources (Ministry of Education of China), School of Chemistry and Pharmacy, Guangxi Normal University, Guilin, P. R. China
E-mail: huangfp2010@163.com

Abstract

Two double-stranded metallo-triangles, Dy9 and Dy24, with hexaple-C10H7PO32− bridges were constructed, and their magnetic properties were explored. Compared with the field-induced relaxation phenomenon of Dy9 templated with a chloride anion, Dy24 templated with a sodium cation exhibited zero-field single-molecule-magnet behavior.

Graphical abstract: Double-stranded metallo-triangles: from anion-templated nonanuclear to cation-templated tetraicosanuclear dysprosium clusters

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Article information

DOI
https://doi.org/10.1039/D3CC04449A
Article type
Communication
Submitted
08 Sep 2023
Accepted
30 Oct 2023
First published
31 Oct 2023

Chem. Commun., 2023,59, 14134-14137

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Double-stranded metallo-triangles: from anion-templated nonanuclear to cation-templated tetraicosanuclear dysprosium clusters

Y. Liu, X. Sun, P. Chen, X. Li, F. Huang, H. Liu and H. Tian, Chem. Commun., 2023, 59, 14134 DOI: 10.1039/D3CC04449A

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