Issue 20, 2023
From the journal:

CrystEngComm

Selective synthesis of two-dimensional semiconductive coordination polymers with silver–sulfur network†

Ryohei Akiyoshi, ORCID logo a   Akinori Saeki, ORCID logo b   Kazuyoshi Ogasawara,a   Hirofumi Yoshikawa, ORCID logo c   Yuiga Nakamura ORCID logo d  and  Daisuke Tanaka ORCID logo *a  

* Corresponding authors

a Department of Chemistry, School of Science, Kwansei Gakuin University, 1 Gakuen Uegahara, Sanda, Hyogo 669-1330, Japan
E-mail: dtanaka@kwansei.ac.jp

b Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan

c Department of Nanotechnology for Suitable Energy, School of Engineering, Kwansei Gakuin University, 1 Gakuen Uegahara, Sanda, Hyogo 669-1330, Japan

d Japan Synchrotron Radiation Research Institute (JASRI), 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5198, Japan

Abstract

Two-dimensional Ag(I) coordination polymers containing a sulfur coordination atom, [Ag(tzdt)]n (KGF-24), and [Ag(tzdt)(TFA)]n (KGF-25) (Htzdt = 1,3-thiazolidine-2-thione, TFA = trifluoroacetate), were synthesized and characterized. Time-resolved microwave conductivity measurements and first-principles calculations revealed that KGF-24 and KGF-25 exhibit charge mobility along their (–Ag–S–)n network.

Graphical abstract: Selective synthesis of two-dimensional semiconductive coordination polymers with silver–sulfur network

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Article information

DOI
https://doi.org/10.1039/D3CE00106G
Article type
Communication
Submitted
04 Feb 2023
Accepted
11 Apr 2023
First published
26 Apr 2023

CrystEngComm, 2023,25, 2990-2994

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Selective synthesis of two-dimensional semiconductive coordination polymers with silver–sulfur network

R. Akiyoshi, A. Saeki, K. Ogasawara, H. Yoshikawa, Y. Nakamura and D. Tanaka, CrystEngComm, 2023, 25, 2990 DOI: 10.1039/D3CE00106G

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