The role of nanoparticle charge in crystallization kinetics and ice adhesion strength for dispersions of detonation nanodiamonds

Abstract

According to the classical nucleation theory, the presence of solid particles in a liquid should facilitate its heterogeneous nucleation upon supercooling. Here, we have analysed the behaviour of aqueous dispersions of detonation diamond nanoparticles (DND) with different signs of the surface charge in supercooled conditions and the frozen state. The behaviours of the diamond nanoparticles with a typical size of 4.5 nm were compared with each other and with deionized water in ice nucleation and ice shear experiments. The presented experimental data and analysis allowed the description of the significant increase in the freezing delay times for positively charged nanoparticles and the sharp decrease for negatively charged ones in comparison to deionized water, based on the peculiarities of the water structure around the nanoparticles and in the vicinity of a superhydrophobic surface. In addition, this approach has allowed the successful explanation of the difference in the practical work of adhesion for deionized water and dispersions of DND with different particle charges.