Prospects of glove-box versus air-processed organic solar cells

Abstract

In the search for alternate green energy sources to offset dependence on fossil fuels, solar energy can certainly meet two needs with one deed: fulfil growing global energy demands due to its non-depletable nature and lower greenhouse gas emissions. As such, third generation thin film photovoltaic technology based organic solar cells (OSCs) can certainly play their role in providing electricity at a competing or lower cost than 1st and 2nd generation solar technologies. As OSCs are still at an early stage of research and development, much focus has been placed on improving power conversion efficiencies (PCEs) inside a controlled environment i.e. a glove-box (GB) filled with an inert gas such as N₂. This was necessary until now, to control and study the local nanomorphology of the spin-coated blend films. For OSCs to compete with other solar energy technologies, OSCs should produce similar or even better morphologies in an open environment i.e. air, such that air-processed OSCs can result in similar PCEs in comparison to their GB-processed counterparts. In this review, we have compared GB- vs. air-processed OSCs from morphological and device physics aspects and underline the key features of efficient OSCs, processed in either GB or air.