Water-based synthesis and nitrate release properties of a ZrIV-based metal–organic framework derived from L-aspartic acid

Temitope Olabisi Abodunrin; Matouŝ Kloda; Jan Demel; Marco Taddei

doi:10.1039/D3DT00380A

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Water-based synthesis and nitrate release properties of a Zr^IV-based metal–organic framework derived from l-aspartic acid†

Temitope Olabisi Abodunrin,

^ab Matouŝ Kloda,

^c Jan Demel

^c and Marco Taddei

*^bd

Author affiliations

* Corresponding authors

^a Department of Physical Sciences, College of Pure and Applied Sciences, Landmark University, P.M.B. 1001, Omu-aran, Kwara State, Nigeria

^b Dipartimento di Chimica e Chimica Industriale, Unità di Ricerca INSTM, Università di Pisa, Via Giuseppe Moruzzi 13, 56124 Pisa, Italy
E-mail: marco.taddei@unipi.it

^c Institute of Inorganic Chemistry of the Czech Academy of Sciences, Husinec-Řež-1001, 250 68 Řež, Czech Republic

^d Centro per l'Integrazione della Strumentazione Scientifica dell'Università di Pisa (CISUP), Pisa, Italy

Abstract

We report the synthesis and characterisation of a cationic metal–organic framework (MOF) based on Zr^IV and L-aspartate and containing nitrate as an extra framework counteranion, named MIP-202-NO₃. The ion exchange properties of MIP-202-NO₃ were preliminarily investigated to evaluate its potential as a platform for controlled release of nitrate, finding that it readily releases nitrate in aqueous solution.

Download options Please wait...

Supplementary files

Supplementary information PDF (2021K)

Article information

DOI: https://doi.org/10.1039/D3DT00380A
Article type: Communication
Submitted: 06 Feb 2023
Accepted: 24 Apr 2023
First published: 24 Apr 2023

Download Citation

Dalton Trans., 2023,52, 5865-5869

Permissions

Request permissions

Water-based synthesis and nitrate release properties of a Zr^IV-based metal–organic framework derived from L-aspartic acid

T. O. Abodunrin, M. Kloda, J. Demel and M. Taddei, Dalton Trans., 2023, 52, 5865 DOI: 10.1039/D3DT00380A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Dalton Transactions