Issue 44, 2023

Reactivity of a series of triaryl borates, B(OArx)3, in hydroboration catalysis

Abstract

In this paper, we compare the reactivity of a series of triaryl borates B(OArx)3 as catalysts for the hydroboration of alkenes and alkynes. It was observed that commercially available B(OPh)3 performed the poorest, whereas catalysts with o-F atoms appeared to perform much better.

Graphical abstract: Reactivity of a series of triaryl borates, B(OArx)3, in hydroboration catalysis

Supplementary files

Article information

Article type
Communication
Submitted
10 Oct 2023
Accepted
15 Oct 2023
First published
20 Oct 2023
This article is Open Access
Creative Commons BY license

Dalton Trans., 2023,52, 16118-16122

Reactivity of a series of triaryl borates, B(OArx)3, in hydroboration catalysis

T. Sokolnicki, M. M. Alharbi, Y. van Ingen, S. Rahim, M. Pramanik, A. Roldan, J. Walkowiak and R. L. Melen, Dalton Trans., 2023, 52, 16118 DOI: 10.1039/D3DT03333C

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