Linear diketones as next-generation biomass-derived platform molecules: from heterogeneous catalytic synthesis to supply of high-end chemicals

Abstract

Extending the catalytic valorization roadmap of platform molecules is one of the core tasks in the development of the biomass conversion field. Through ongoing research efforts, the transformation system of biomass-derived platform molecules has been well established and is gradually becoming relatively mature. In this context, it is of great practical interest to further explore next-generation platform molecules and their valorization pathways that have recently emerged. Linear diketones, usually derived from biomass and their C₆ furan compounds, are one of the novel platform molecules that have been recently spotlighted for the synthesis of high-end chemicals due to their huge valorization potential. Herein, we intend to underline the crucial platform role that linear diketones, i.e., 2,5-hexanedione (HD) and 1-hydroxy-2,5-hexanedione (HHD), play in extending the biomass valorization roadmap to a broader one. Perspectives are concentrated on elucidating the heterogeneous tandem conversion system of biomass and its derived C₆ furan compounds to HD and HHD. Also, we further demonstrate the diverse valorization routes of HD and HHD to high-end chemicals for various applications. The insights presented in this paper may contribute to highlighting the bright future of linear diketones in constructing a sustainable biomass valorization system.