Issue 11, 2023

Influence of anions on the synthesis of Cu(i)-based coordination polymers along with a series of derived materials for selective photocatalytic properties

Abstract

Coordination polymers (CPs) are a scientifically compelling and evolving class of highly crystalline materials. Owing to their controllable structures and morphologies, CPs can be used as a type of uniformly and periodically atom-distributed precursor and efficient self-sacrificial template to fabricate porous-carbon-related functional materials. In this work, we have used CuCl2·2H2O or Cu(NO3)2·3H2O to combine with N,N′-bis(3-pyridinecarboxamide)-1,2-cyclohexane (3-bpah) to construct Cu(I)-based CPs, namely [Cu(3-bpah)Cl]·H2O (1) and [Cu(3-bpah)(NO3)] (2), respectively. We have studied the effect of anions on the structure of the compound in detail. Moreover, the two Cu(I)-based CPs were used as precursors for the preparation of derived materials; then foreign elements were doped into the intrinsic CP-based derived materials and their properties were explored. The adsorption capacities and photocatalytic activities were studied in detail.

Graphical abstract: Influence of anions on the synthesis of Cu(i)-based coordination polymers along with a series of derived materials for selective photocatalytic properties

Supplementary files

Article information

Article type
Paper
Submitted
27 Mar 2023
Accepted
10 Jul 2023
First published
11 Jul 2023

Mol. Syst. Des. Eng., 2023,8, 1388-1401

Influence of anions on the synthesis of Cu(I)-based coordination polymers along with a series of derived materials for selective photocatalytic properties

X. Zhang, J. Cui, Y. Liu, W. Li, Y. Liu, H. Xiang and J. Luan, Mol. Syst. Des. Eng., 2023, 8, 1388 DOI: 10.1039/D3ME00047H

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