Self-healing of electrical damage in insulating robust epoxy containing dynamic fluorine-substituted carbamate bonds for green dielectrics

Abstract

Power systems and electrical grids are critical for the development of renewable energy. Electrical treeing is one of the major factors that lead to electrical damage in insulating dielectrics and decline in the reliability of power equipment and ultimately results in catastrophic failure. Here, we demonstrate that bulk epoxy damaged by electrical treeing is able to efficiently heal repeatedly to recover its original robust performance. The classical dilemma between the insulating properties and electrical-damage healability is overcome by dynamic fluorinated carbamate bonds. Moreover, the dynamic bond enables the epoxy to have admirable degradability, which is demonstrated to be used as an attractive green degradable insulation coating. When used as a matrix for fiber-reinforced composites, the reclaimed glass fibers after decomposing the epoxy maintained their original morphology and functionality. This design provides a novel approach for developing smart and green dielectrics to enhance the reliability, sustainability and lifespan of power equipment and electronics.