Lignin-based acrylate adhesive without organic solvent processing
Abstract
As a green adhesive, lignin-based acrylate adhesives have a promising future in substitute commercial adhesives owing to their cost-effectiveness, and environmental friendliness. In this work, a green and convenient strategy for the fabrication of lignin-based acrylate adhesives was developed via the introduction of lauryl methacrylate with a low glass transition temperature (−62 °C) into the chemical structure of lignin to improve the compatibility, toughness, strength and wettability of lignin-based adhesives. With the introduction of lauryl methacrylate, the shear strength of the lignin-based adhesive reached 5.10 MPa, which is 114% higher than the traditional acrylate adhesive. Moreover, the lignin-based adhesive also exhibits excellent hydrophobicity and high shear strength after 12 h of immersion in water. This work not only provides a new strategy for the fabrication of economical, green, and sustainable lignin-based acrylate adhesives without the participation of organic solvents, but also achieves the value-added utilization of lignin.