α-cyclodextrin dissolved in water binds methane giving crystals of a 1 : 1 complex in up to 57% yield. The binding constant was Ka = 21 (± 1.0) M−1. 3A,6A,3D,6D-dianhydro-α-cyclodextrin which has a smaller cavity than α-cyclodextrin binds methane three fold better (Ka = 75 (± 25) M−1)
C. H. Jessen, J. Bendix, T. B. Nannestad, H. N. Bordallo, M. J. Pedersen, C. M. Pedersen and M. Bols, New J. Chem., 2023, 47, 14624 DOI: 10.1039/D3NJ01843A
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