Issue 48, 2023
From the journal:

Nanoscale

Iron-incorporated metal–organic frameworks for oxidative cleavage of trans-anethole to p-anisaldehyde†

Jun Xiong,a   Xin Yuan,a   Min-Hua Zong,a   Xiaoling Wu*ab  and  Wen-Yong Lou ORCID logo *ab  

* Corresponding authors

a Lab of Applied Biocatalysis, National Engineering Research Center of Wheat and Corn Further Processing, School of Food Science and Engineering, South China University of Technology, No. 381 Wushan Road, Guangzhou 510640, Guangdong, China

b Guangdong Province Key Laboratory for Green Processing of Natural Products and Product Safety, South China University of Technology, No. 381 Wushan Road, Guangzhou 510640, Guangdong, China

Abstract

An iron-incorporated Zn-MOF catalyst Zn-bpydc·Fe was fabricated for the oxidative cleavage of trans-anethole to p-anisaldehyde under facile conditions, under 1 atm of O2. The Fe coordinated bipyridine serves as the catalytically active center inside the structural skeleton of Zn-MOFs. This work affords a new avenue for the mild oxidation of olefins.

Graphical abstract: Iron-incorporated metal–organic frameworks for oxidative cleavage of trans-anethole to p-anisaldehyde

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Article information

DOI
https://doi.org/10.1039/D3NR04795D
Article type
Communication
Submitted
22 Sep 2023
Accepted
29 Nov 2023
First published
05 Dec 2023

Nanoscale, 2023,15, 19493-19498

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Iron-incorporated metal–organic frameworks for oxidative cleavage of trans-anethole to p-anisaldehyde

J. Xiong, X. Yuan, M. Zong, X. Wu and W. Lou, Nanoscale, 2023, 15, 19493 DOI: 10.1039/D3NR04795D

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