Activated vinylcyclopropanes can form zwitterionic π-allylmetal species in the presence of transition metals and are widely used in organic synthesis. A nickel-catalyzed asymmetric allylation of secondary phosphine oxides with vinylcyclopropanes was described. Tertiary phosphine oxide products could be obtained with up to 91% yield and 92% ee.
Z. Huang, X. Liu, R. Cui and Q. Zhang, Org. Biomol. Chem., 2023, 21, 3096 DOI: 10.1039/D3OB00389B
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