Pd-catalyzed decarboxylative 1,4-addition reactions of benzofuran-based azadienes with allyl phenyl carbonates

Lu-Yu Cai; Xiu-Qing Song; Kuo Wang; Yue Zhang; Hong-Wu Zhao

doi:10.1039/D3OB00968H

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Pd-catalyzed decarboxylative 1,4-addition reactions of benzofuran-based azadienes with allyl phenyl carbonates†

Lu-Yu Cai,^a Xiu-Qing Song,^b Kuo Wang,^a Yue Zhang^a and Hong-Wu Zhao

*^a

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* Corresponding authors

^a College of Life Science and Bio-engineering, Beijing University of Technology, Beijing 100124, P. R. China
E-mail: hwzhao@bjut.edu.cn
Fax: +86-10-6739-6211
Tel: +86-10-6739-6211

^b Large-scale Instruments and Equipments Sharing Platform, Beijing University of Technology, Beijing 100124, P. R. China

Abstract

Under the catalysis of Pd(OAc)₂/dppf/Na₂CO₃, the decarboxylative 1,4-addition reaction of benzofuran-based azadienes with allyl phenyl carbonates took place easily and delivered the desired products in reasonable chemical yields. The chemical structure of the target compounds was clearly identified by single crystal X-ray structural analysis.

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DOI: https://doi.org/10.1039/D3OB00968H
Article type: Paper
Submitted: 19 Jun 2023
Accepted: 23 Jul 2023
First published: 25 Jul 2023

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Org. Biomol. Chem., 2023,21, 6556-6564

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Pd-catalyzed decarboxylative 1,4-addition reactions of benzofuran-based azadienes with allyl phenyl carbonates

L. Cai, X. Song, K. Wang, Y. Zhang and H. Zhao, Org. Biomol. Chem., 2023, 21, 6556 DOI: 10.1039/D3OB00968H

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Organic & Biomolecular Chemistry

Pd-catalyzed decarboxylative 1,4-addition reactions of benzofuran-based azadienes with allyl phenyl carbonates†

Abstract

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Pd-catalyzed decarboxylative 1,4-addition reactions of benzofuran-based azadienes with allyl phenyl carbonates

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