Synthesis, characterization and properties of a novel environmentally friendly ternary hydrophilic copolymer

Abstract

A novel environmentally friendly scale inhibitor was synthesized by the free radical polymerization of itaconic acid (IA), acrylamide (AM), and sodium p-styrene sulfonate (SSS). The structures of the copolymers were characterized using FTIR, UV, and ¹H-NMR, which proved successful in obtaining the expected target structures. The synthesis conditions such as monomer ratio, initiator dosage, titration time, and reaction temperature were optimized by the static scale inhibition method, and the expected polymeric scale inhibitor with a competent scale inhibition performance was obtained. The copolymer conversions at different temperatures were obtained indirectly by bromination titration, and the relationship between the molecular weight of the polymer and the scale inhibition performance at different reaction temperatures was also investigated by GPC. The results showed that the copolymer had a good ability to control calcium carbonate scaling, and the inhibition rate of CaCO₃ reached 84.7% at a dose of 30 mg L⁻¹. The microscopic morphology and structure of calcium scales were analyzed by SEM, FTIR, and XRD, and it was concluded that the copolymer could change the crystallization path of calcium carbonate from stable calcite to vaterite. That could be dispersed in water. The proposed inhibition mechanism suggests that surface complexation between polymer functional groups and Ca²⁺ leads to excellent solubility of the complexes. These findings suggest that the prepared green copolymers have great potential for oilfield applications.