Poly(acrylic acid-co-2-acrylamido-2-methyl-1-propanesulfonic acid)-grafted chitosan hydrogels for effective adsorption and photocatalytic degradation of dyes

Abstract

As a result of the growth of industrialization and urbanization, the water ecosystem is contaminated by various pollutants, including heavy metal ions and dyes. The use of low-cost and environmentally friendly dye adsorbents has been investigated. A hydrogel was fabricated via graft polymerization of acrylic acid (AA) and 2-acrylamido-2-methyl-1-propanesulfonic acid (AMPS) onto chitosan. The hydrogel was used as a dye adsorbent and support for a zinc oxide (ZnO) powder photocatalyst. The adsorption capacity of the bare hydrogel was greater towards cationic dyes than anionic dyes. Grafting P(AA-co-AMPS) exhibited a 23-time increase in adsorption capacity towards crystal violet (CV) compared to pristine chitosan. The effect of the AA–AMPS molar ratio on CV adsorption was studied. A hydrogel with an AA–AMPS ratio of 10 : 1 had the highest adsorption capacity towards CV in water, removing 91% of the dye in 12 h. The maximum adsorption capacity was 2023 mg g⁻¹. The adsorption kinetics and isotherm were described by the pseudo-second-order model and the Langmuir model, respectively. ZnO particles were in situ synthesized within the 10 : 1 hydrogel to facilitate the recovery of the photocatalyst. The ZnO hydrogel composite could remove 95% and 92% of CV from solutions on the 1st and 2nd cycle, respectively. In addition, the hydrogel composite containing only 8.7 wt% of ZnO particles effectively degraded adsorbed CV under sunlight and could be reused without requiring a chemical regeneration or photocatalyst recovery procedure. This hydrogel composite is an effective dual-functional material for the adsorption and photodegradation of dye pollutants in wastewater.