Solution-state mechanochromic luminescence of Pt(ii)-complexes displayed within micellar aromatic capsules

Abstract

Mechanochromic luminescence (MCL) is an intrinsic phenomenon in the solid state and thus has been hardly observed in solution so far. Here we report that arylethynyl Pt(II)-complexes with an NCN-pincer ligand are efficiently encapsulated by micellar aromatic capsules in water, through a simple grinding protocol with bent amphiphiles. When a bent pentamethylbenzene-based amphiphile is employed as an optimized capsule component, the resultant host–guest composite, with an average diameter of ∼4 nm, is obtained in water at room temperature. Notably, the nanocomposite displays strong red emission (Φ = 33%, λ_max = 700 nm) derived from MCL via intermolecular Pt(II)⋯Pt(II) interactions even under aerobic aqueous conditions, in sharp contrast to the free Pt(II)-complex with weak green emission (Φ = 4%, λ_max = 500 nm) in CH₂Cl₂. Moreover, enhancement of the solution-state MCL (up to Φ = 48%) can be achieved by coencapsulation of the Pt(II)-complexes with carbazole derivatives by the capsule in water. This study provides the first example of “solution-state” mechanochromic luminescence, capable of facilely tuning its intensity and wavelength, among the intensive studies of various solid-state MCL reported previously.