MnO/TiO2/C/N-CNTs derived from Mn-doped Ti MOFs for simultaneous detection of catechol and hydroquinone

Abstract

Mn-doped Ti-based MOFs (MnTi MOFs) were synthesized by a solvothermal method, and calcined at high temperature after being mixed with pre-prepared PPy nanotubes to give MnO/TiO₂/C/N-CNTs composites. The composites were studied by SEM, XRD, XPS and FTIR. Based on these composites, a new electrochemical sensor was prepared, which has good electrocatalytic ability for the redox of catechol (CC) and hydroquinone (HQ), and can detect CC and HQ simultaneously. The results showed that the oxidation peak current of CC and HQ increased linearly in the concentration range of 0.50–120.00 μM. The detection limits were 0.033 μM and 0.019 μM, respectively. The constructed sensor has been successfully used for the simultaneous detection of CC and HQ in lake water and tap water, and has a good recovery rate.