Solution and solid-state characterization of rare silyluranium(iii) complexes†
Abstract
A uranium(III) silylate complex [K(DME)4][UI2{(Si(SiMe3)2SiMe2)2O}] (1) was stabilized by the addition of 18-crown-6, forming [K(18-crown-6)][UI2{(Si(SiMe3)2SiMe2)2O}] (1-crown). Crystallization under multiple conditions resulted in three distinct molecular structures. Compound 1-crown was further characterized in the solution state via1H, 13C, and 29Si NMR spectroscopy, and electronic absorption spectroscopy.