Issue 48, 2024

Hierarchical chiral MOFs with the induced chirality of AIE ligands exhibiting non-reciprocal CPL

Abstract

Two pairs of chiral MOFs with hierarchical chiral structures were constructed through assembly of achiral AIE-type multidentate linkers and chiral camphoric acid. Non-reciprocal circularly polarized luminescence (CPL) can be observed on the macroscopic due to the coexistence of optical anisotropic and chiroptical nature. This study provides a new perspective to recognize and construct chiral crystalline materials.

Graphical abstract: Hierarchical chiral MOFs with the induced chirality of AIE ligands exhibiting non-reciprocal CPL

Supplementary files

Article information

Article type
Communication
Submitted
27 Feb 2024
Accepted
10 May 2024
First published
14 May 2024

Chem. Commun., 2024,60, 6182-6185

Hierarchical chiral MOFs with the induced chirality of AIE ligands exhibiting non-reciprocal CPL

H. Fu, D. Ren, K. Zhang, S. Wang, X. Yang, Q. Ding and Y. Wu, Chem. Commun., 2024, 60, 6182 DOI: 10.1039/D4CC00925H

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