Lewis base adducts of NpCl4

Lauren M. Lopez; Madeleine C. Uible; Matthias Zeller; Suzanne C. Bart

doi:10.1039/D4CC01560F

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Lewis base adducts of NpCl₄†

Lauren M. Lopez,

‡^a Madeleine C. Uible,

‡^a Matthias Zeller^a and Suzanne C. Bart

*^a

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* Corresponding authors

^a H.C. Brown Laboratory of Chemistry, Department of Chemistry, Purdue University, 560 Oval Drive, West Lafayette, IN 47907, USA
E-mail: sbart@purdue.edu

Abstract

Np(IV) Lewis base adducts were prepared by ligand substitution of NpCl₄(DME)₂. Using acetonitrile and pyridine, NpCl₄(MeCN)₄ (1) and NpCl₄(pyr)₄ (2) were isolated, respectively. Addition of t-butylbipyridine and triphenylphosphine oxide generated the respective Lewis base adducts, NpCl₄(^tBuBipy)₂ (3) and NpCl₄(OPPh₃)₂ (4). All species were fully characterized using spectroscopic and structural analyses.

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Article information

DOI: https://doi.org/10.1039/D4CC01560F
Article type: Communication
Submitted: 05 Apr 2024
Accepted: 01 May 2024
First published: 03 May 2024
This article is Open Access

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Chem. Commun., 2024,60, 5956-5959

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Lewis base adducts of NpCl₄

L. M. Lopez, M. C. Uible, M. Zeller and S. C. Bart, Chem. Commun., 2024, 60, 5956 DOI: 10.1039/D4CC01560F

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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Chemical Communications