Issue 65, 2024
From the journal:

Chemical Communications

A neutral crystalline imino-substituted silyl radical†

Fiona J. Kiefer,a   Arseni Kostenko, ORCID logo a   Richard Holzner ORCID logo a  and  Shigeyoshi Inoue ORCID logo *a  

* Corresponding authors

a TUM School of Natural Sciences, Department of Chemistry, Wacker-Institute of Silicon Chemistry and Catalysis Research Center, Technische Universität München, Lichtenbergstraße 4, 85748 Garching bei München, Germany
E-mail: s.inoue@tum.de

Abstract

The neutral three-coordinated imino(silyl)silyl radical was isolated from the reaction of N-heterocyclic iminosilicon tribromide (ItBuN-SiBr3) with NaSitBu2Me. The radical was fully characterized by X-ray crystallography and electron paramagnetic resonance spectroscopy and supported by quantum chemical calculations.

Graphical abstract: A neutral crystalline imino-substituted silyl radical

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D4CC02167C
Article type
Communication
Submitted
04 May 2024
Accepted
09 Jul 2024
First published
10 Jul 2024
This article is Open Access
Creative Commons BY license

Chem. Commun., 2024,60, 8577-8580

Permissions

Request permissions

A neutral crystalline imino-substituted silyl radical

F. J. Kiefer, A. Kostenko, R. Holzner and S. Inoue, Chem. Commun., 2024, 60, 8577 DOI: 10.1039/D4CC02167C

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements