Issue 92, 2024
From the journal:

Chemical Communications

Double dehydrogenative coupling of amino alcohols with primary alcohols under Mn(i) catalysis†

Ganesan Sivakumar, ORCID logo a   Abhijith Karattil Suresh,a   Smruti Rekha Padhya  and  Ekambaram Balaraman ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Indian Institute of Science Education and Research (IISER) Tirupati, Tirupati – 517507, Andhra Pradesh, India
E-mail: eb.raman@iisertirupati.ac.in

Abstract

Herein, we unveil a method for synthesizing substituted pyrrole and pyrazine compounds via a double dehydrogenative coupling of amino alcohols with primary alcohols, facilitated by Mn(I)–PNP catalysis, which uniquely enables the simultaneous formation of C–C and C–N bonds.

Graphical abstract: Double dehydrogenative coupling of amino alcohols with primary alcohols under Mn(i) catalysis

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Article information

DOI
https://doi.org/10.1039/D4CC03595J
Article type
Communication
Submitted
19 Jul 2024
Accepted
22 Oct 2024
First published
23 Oct 2024
This article is Open Access
Creative Commons BY license

Chem. Commun., 2024,60, 13606-13609

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Double dehydrogenative coupling of amino alcohols with primary alcohols under Mn(I) catalysis

G. Sivakumar, A. K. Suresh, S. R. Padhy and E. Balaraman, Chem. Commun., 2024, 60, 13606 DOI: 10.1039/D4CC03595J

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