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3D organic–inorganic hybrid heterojunctions of 1D carbon nitride (g-C3N4) nanoneedles anchoring on 2D Ti3C2 MXene nanosheets have been constructed via a green molten salt treatment. The Ti3C2 MXene nanosheets and molten salt treatment guide the formation of ordered nanoneedle-like g-C3N4. Both the formed heterojunctions and the nanoneedle-like structures contribute charge separation and transfer for superior photocatalytic H2 evolution.

Graphical abstract: The synthesis of 3D organic–inorganic hybrid heterojunctions of g-C3N4 nanoneedles@Ti3C2 MXene with superior photocatalytic H2 evolution

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