From the journal:

Chemical Communications

Interphase formation versus fluoride-ion insertion in tunnel-structured transition metal antimonites†

Alice R. Giem,ab   Jaime R. Ayala, ORCID logo ab   Jingxiang Cheng, ORCID logo ab   Conan Weiland,c   Cherno Jaye,c   Daniel A. Fischerc  and  Sarbajit Banerjee ORCID logo *ab  

* Corresponding authors

a Department of Chemistry, Texas A&M University, College Station, TX, USA
E-mail: banerjee@chem.tamu.edu

b Department of Material Science & Engineering, Texas A&M University, College Station, TX 77843, USA

c Material Measurement Laboratory, National Institute of Standards and Technology, Gaithersburg, MD 20899, USA

Abstract

Fluoridating reagents are used to model interfacial reactions in fluoride-ion batteries. Topochemical F-ion insertion is seen for one-dimensional (1D) tunnel-structured FeSb2O4 but interphase formation comprising antimony (oxy)fluorides is observed for MnSb2O4.

Graphical abstract: Interphase formation versus fluoride-ion insertion in tunnel-structured transition metal antimonites

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Article information

DOI
https://doi.org/10.1039/D4CC04331F
Article type
Communication
Submitted
24 Aug 2024
Accepted
28 Oct 2024
First published
06 Nov 2024
This article is Open Access
Creative Commons BY license

Chem. Commun., 2024, Advance Article

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Interphase formation versus fluoride-ion insertion in tunnel-structured transition metal antimonites

A. R. Giem, J. R. Ayala, J. Cheng, C. Weiland, C. Jaye, D. A. Fischer and S. Banerjee, Chem. Commun., 2024, Advance Article , DOI: 10.1039/D4CC04331F

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