Issue 98, 2024
From the journal:

Chemical Communications

Interphase formation versus fluoride-ion insertion in tunnel-structured transition metal antimonites†

Alice R. Giem,ab   Jaime R. Ayala, ORCID logo ab   Jingxiang Cheng, ORCID logo ab   Conan Weiland,c   Cherno Jaye,c   Daniel A. Fischerc  and  Sarbajit Banerjee ORCID logo *ab  

* Corresponding authors

a Department of Chemistry, Texas A&M University, College Station, TX, USA
E-mail: banerjee@chem.tamu.edu

b Department of Material Science & Engineering, Texas A&M University, College Station, TX 77843, USA

c Material Measurement Laboratory, National Institute of Standards and Technology, Gaithersburg, MD 20899, USA

Abstract

Fluoridating reagents are used to model interfacial reactions in fluoride-ion batteries. Topochemical F-ion insertion is seen for one-dimensional (1D) tunnel-structured FeSb2O4 but interphase formation comprising antimony (oxy)fluorides is observed for MnSb2O4.

Graphical abstract: Interphase formation versus fluoride-ion insertion in tunnel-structured transition metal antimonites

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Article information

DOI
https://doi.org/10.1039/D4CC04331F
Article type
Communication
Submitted
24 Aug 2024
Accepted
28 Oct 2024
First published
06 Nov 2024
This article is Open Access
Creative Commons BY license

Chem. Commun., 2024,60, 14589-14592

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Interphase formation versus fluoride-ion insertion in tunnel-structured transition metal antimonites

A. R. Giem, J. R. Ayala, J. Cheng, C. Weiland, C. Jaye, D. A. Fischer and S. Banerjee, Chem. Commun., 2024, 60, 14589 DOI: 10.1039/D4CC04331F

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