Mn-mediated reductive cross-coupling of organic bromides with 2-bromo-1,3,2-diazaphospholene was developed for efficient construction of C-P bonds under mild conditions. Mechanistic studies suggested bromides are activated by in situ formed bis-diazaphospholene via hybrid radical and polar mechanisms.
L. Dong, B. Zhong, Y. Zhang, J. Yang and J. Cheng, Chem. Commun., 2024, Accepted Manuscript , DOI: 10.1039/D4CC04750H
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