Exploring the effect of pressure on the crystal structure and caloric properties of the molecular ionic hybrid [(CH3)3NOH]2[CoCl4]

Abstract

The hybrid metal halide [(CH3)3NOH]2CoCl4 exhibits a first-order phase transition at T ∼ 343 K. Its crystal structure and caloric properties respond significantly to moderate pressures (1–1000 bar), demonstrating potential for applications in emerging solid-state refrigeration technologies.

Graphical abstract: Exploring the effect of pressure on the crystal structure and caloric properties of the molecular ionic hybrid [(CH3)3NOH]2[CoCl4]

Supplementary files

Article information

Article type
Communication
Submitted
30 Sep 2024
Accepted
31 Oct 2024
First published
06 Nov 2024
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2024, Advance Article

Exploring the effect of pressure on the crystal structure and caloric properties of the molecular ionic hybrid [(CH3)3NOH]2[CoCl4]

P. Dafonte-Rodríguez, I. Delgado-Ferreiro, J. García-Ben, A. Ferradanes-Martínez, M. Gelpi, J. Walker, C. J. McMonagle, S. Castro-García, M. A. Señarís-Rodríguez, J. M. Bermúdez-García and M. Sánchez-Andújar, Chem. Commun., 2024, Advance Article , DOI: 10.1039/D4CC05125D

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