Zirconium metal–organic framework photocatalysis with TEMPO for blue light-powered aerobic sulfoxidation

Bing Zeng; Yuexin Wang; Kanghui Xiong; Keke Zhang; Siyu Zhang; Xianjun Lang

doi:10.1039/D4CC05173D

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Zirconium metal–organic framework photocatalysis with TEMPO for blue light-powered aerobic sulfoxidation†

Bing Zeng,^a Yuexin Wang,^a Kanghui Xiong,^a Keke Zhang,^a Siyu Zhang^a and Xianjun Lang

*^a

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* Corresponding authors

^a Hubei Key Lab on Organic and Polymeric Optoelectronic Materials, College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China
E-mail: xianjunlang@whu.edu.cn

Abstract

A zirconium metal–organic framework (MOF), NU-1003, along with TEMPO (2,2,6,6-tetramethylpiperidine-N-oxyl), is constructed as a system of cooperative photocatalysis for blue light-powered aerobic sulfoxidation. The incorporation of 4 mol% of TEMPO enhances the hole transfer and thereby aerobic sulfoxidation by NU-1003 photocatalysis, demonstrating the pivotal role of a redox mediator in transforming an established MOF.

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Article information

DOI: https://doi.org/10.1039/D4CC05173D
Article type: Communication
Submitted: 01 Oct 2024
Accepted: 31 Oct 2024
First published: 11 Nov 2024

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Chem. Commun., 2024,60, 14061-14064

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Zirconium metal–organic framework photocatalysis with TEMPO for blue light-powered aerobic sulfoxidation

B. Zeng, Y. Wang, K. Xiong, K. Zhang, S. Zhang and X. Lang, Chem. Commun., 2024, 60, 14061 DOI: 10.1039/D4CC05173D

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Chemical Communications

Zirconium metal–organic framework photocatalysis with TEMPO for blue light-powered aerobic sulfoxidation†

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Zirconium metal–organic framework photocatalysis with TEMPO for blue light-powered aerobic sulfoxidation

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