Issue 4, 2024
From the journal:

Dalton Transactions

A copper(i) thiocyanate-based photoresponsive semiconducting 2D coordination polymer†

Tomoki Nishiyama, ORCID logo a   Hirotaka Kitoh-Nishioka, ORCID logo b   Senku Tanaka, ORCID logo bc   Masahiko Maekawa, ORCID logo ac   Takayoshi Kuroda-Sowa,a   Masaki Yoshida, ORCID logo d   Masako Kato ORCID logo d  and  Takashi Okubo ORCID logo *bc  

* Corresponding authors

a Department of Chemistry, Kindai University, 3-4-1 Kowakae, Higashi-Osaka, Osaka 577-8502, Japan

b Department of Energy and Materials, Kindai University, 3-4-1 Kowakae, Higashi-Osaka, Osaka 577-8502, Japan

c Research Institute for Science and Technology, Kindai University, 3-4-1 Kowakae, Higashi-Osaka, Osaka 577-8502, Japan

d Department of Applied Chemistry for Environment, School of Biological and Environmental Sciences, Kwansei Gakuin University, 1 Gakuen Uegahara, Sanda, Hyogo 669-1330, Japan

Abstract

A coordination polymer, [Cu(SCN)(iqi)]n (iqi = isoquinoline), containing copper(I) thiocyanate and a nitrogen-containing π-conjugated ligand, iqi, has been synthesized and its physical properties were evaluated. This coordination polymer has a two-dimensional (2D) sheet structure consisting of copper(I) thiocyanate and shows photoluminescence derived from 3MLCT and photoconductive properties.

Graphical abstract: A copper(i) thiocyanate-based photoresponsive semiconducting 2D coordination polymer

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Article information

DOI
https://doi.org/10.1039/D3DT03125J
Article type
Communication
Submitted
23 Sep 2023
Accepted
04 Dec 2023
First published
29 Dec 2023

Dalton Trans., 2024,53, 1445-1448

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A copper(I) thiocyanate-based photoresponsive semiconducting 2D coordination polymer

T. Nishiyama, H. Kitoh-Nishioka, S. Tanaka, M. Maekawa, T. Kuroda-Sowa, M. Yoshida, M. Kato and T. Okubo, Dalton Trans., 2024, 53, 1445 DOI: 10.1039/D3DT03125J

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