Planar three-coordinate iron(II) complexes supported by sterically demanding –Si(SiMe3)2(SiMe2tBu) ligands

Reon Ishii; Yusuke Sunada

doi:10.1039/D3DT04130A

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Planar three-coordinate iron(ii) complexes supported by sterically demanding –Si(SiMe₃)₂(SiMe₂^tBu) ligands†

Reon Ishii^a and Yusuke Sunada

*^abc

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* Corresponding authors

^a Department of Applied Chemistry, School of Engineering, The University of Tokyo, 4-6-1, Komaba, Meguro-ku, Tokyo 153-8505, Japan

^b Institute of Industrial Science, The University of Tokyo, 4-6-1, Komaba, Meguro-ku, Tokyo 153-8505, Japan

^c JST PRESTO, 4-1-8 Honcho, Kawaguchi, Saitama, Japan

Abstract

Sterically demanding organosilyl ligands support the formation of coordinatively unsaturated complexes. In this study, we found that using the ligand –Si(SiMe₃)₂(SiMe₂^tBu) affords exclusively planar three-coordinate iron bis(silyl) complexes that show good catalytic performance in the hydrosilylation of acetophenone.

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Article information

DOI: https://doi.org/10.1039/D3DT04130A
Article type: Communication
Submitted: 11 Dec 2023
Accepted: 22 Dec 2023
First published: 01 Jan 2024
This article is Open Access

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Dalton Trans., 2024,53, 1421-1424

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Planar three-coordinate iron(II) complexes supported by sterically demanding –Si(SiMe₃)₂(SiMe₂^tBu) ligands

R. Ishii and Y. Sunada, Dalton Trans., 2024, 53, 1421 DOI: 10.1039/D3DT04130A

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