Exploring the carbonic anhydrase-mimetic [(PMDTA)2Zn II2(OH−)2]2+ for nitric oxide monooxygenation†
Sandip
Das 
a
and
Pankaj
Kumar
*a
a
and
Pankaj
Kumar
*a
Abstract
In biology, nitrite (NO2−) serves as a storage pool of nitric oxide (NO); however, the formation of NO2− from NO is still under investigation. Here, we report the NO monooxygenation (NOM) reaction of a ZnII–hydroxide complex (1), producing a ZnII–nitrito complex {2, (ZnII–NO2−)} + H2.
![Graphical abstract: Exploring the carbonic anhydrase-mimetic [(PMDTA)2ZnII2(OH−)2]2+ for nitric oxide monooxygenation](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=D4DT00407H&imageInfo.ImageIdentifier.Year=2024)
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