A novel Cu(I)-based coordination polymer for efficient photocatalytic oxidation of C(sp3)–H bonds

Jiangtao Deng; Huilin Huang; Zhentao Li; Xu Jing; Chunying Duan

doi:10.1039/D4DT01257G

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

A novel Cu(i)-based coordination polymer for efficient photocatalytic oxidation of C(sp³)–H bonds†

Jiangtao Deng,^a Huilin Huang,^a Zhentao Li,^a Xu Jing

*^a and Chunying Duan

Author affiliations

* Corresponding authors

^a State Key Laboratory of Fine Chemicals, College of Chemistry, Dalian University of Technology, P. R. China
E-mail: xjing@dlut.edu.cn

Abstract

A novel coordination polymer CuCl-Pyhc was successfully synthesized, which can catalyze efficient and selective oxidation of C(sp³)–H bonds under mild conditions, exhibiting exceptional stability and remarkable recyclability. Furthermore, CuCl-Pyhc can mimic natural monooxygenases and activate oxygen into singlet oxygen (¹O₂).

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/D4DT01257G
Article type: Communication
Submitted: 29 Apr 2024
Accepted: 28 May 2024
First published: 03 Jun 2024

Download Citation

Dalton Trans., 2024,53, 10055-10059

Permissions

Request permissions

A novel Cu(I)-based coordination polymer for efficient photocatalytic oxidation of C(sp³)–H bonds

J. Deng, H. Huang, Z. Li, X. Jing and C. Duan, Dalton Trans., 2024, 53, 10055 DOI: 10.1039/D4DT01257G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Dalton Transactions