A nickel(II) octabutoxyphthalocyanine complex demonstrating ligand-centered redox activity and pH dependence is reported and investigated as an electrocatalyst for hydrogen evolution from water. Spectro- and electrochemical methods were implemented to further elucidate the nature of the pH dependence and catalytic mechanism.
J. Brown and D. Richeson, Dalton Trans., 2024, 53, 14587 DOI: 10.1039/D4DT01419G
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