Revolutionizing energy storage with advanced reduced graphene oxide-wrapped MnSe@CoSe@FeSe2 nanowires

Abstract

Thanks to their good redox activity properties and exceptional conductivity, metal selenides (MSs) have attracted great attention as prospective positive electrodes for hybrid supercapacitors. However, they demonstrate low-rate capacities and poor endurance. Nanomaterials fabricated from MSs and reduced graphene oxide (rGO) with a porous skeleton can effectively mitigate the above-mentioned problems. Herein, porous MnSe@CoSe@FeSe₂ nanowires wrapped with rGO on nickel foam (NF@MCFS-rGO) are manufactured as a binder-free electrode for a hybrid supercapacitor. The obtained NF@MCFS-rGO, acting as a positive electrode, has distinct advantages such as (1) the porous nanowires are helpful for fast electrolyte penetration, (2) the conductivity of the MCFS is further improved when combined with rGO, and (3) wrapping MCFS within the rGO endows the nanomaterial with much better structural durability. Capitalizing on the high conductivity of the rGO and the porous morphology, the fabricated NF@MCFS-rGO manifests impressive characteristics with a capacitance of 1830 F g⁻¹ at 1 A g⁻¹ and only 6.75% capacitance loss within 10 000 cycles. By matching NF@MCFS-rGO with activated carbon (AC), the fabricated apparatus (AC\\NF@MCFS-rGO) reveals an energy density (E_D) of 64.6 W h kg⁻¹ and a long lastingness of 90.55% after 10 000 cycles.