Issue 40, 2024
From the journal:

Dalton Transactions

Efficient hydrogenation of ketones over the diaminophosphino manganese complex†

Yu Zhang,a   Bin Li, ORCID logo b   Tao Wang,a   Ning Duan,a   Jianwei Zheng,c   Hao Li, ORCID logo a   Fengjun Zhang ORCID logo a  and  Xiaolong Fang ORCID logo *a  

* Corresponding authors

a Anhui Province Engineering Laboratory of Advanced Building Materials, College of Materials and Chemical Engineering, Anhui Jianzhu University, Hefei, China
E-mail: xlfang@stu.xmu.edu.cn

b Key Laboratory of Light Energy Conversion Materials of Hunan Province, College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha, China

c State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, China

Abstract

Herein, we synthesized new manganese(I) complexes coordinated with the tetradentate ligand PNNP. The complexes show higher activity and excellent substituent tolerance in contrast to their manganese counterparts and are applicable in the hydrogenation of a wide range of aromatic, aliphatic and heterocyclic ketones to their corresponding alcohols.

Graphical abstract: Efficient hydrogenation of ketones over the diaminophosphino manganese complex

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Article information

DOI
https://doi.org/10.1039/D4DT02297A
Article type
Communication
Submitted
12 Aug 2024
Accepted
13 Sep 2024
First published
18 Sep 2024

Dalton Trans., 2024,53, 16475-16479

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Efficient hydrogenation of ketones over the diaminophosphino manganese complex

Y. Zhang, B. Li, T. Wang, N. Duan, J. Zheng, H. Li, F. Zhang and X. Fang, Dalton Trans., 2024, 53, 16475 DOI: 10.1039/D4DT02297A

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