The homoleptic hydroxy-pyridine functionalized Co(III)–NHC complex (2) demonstrates extraordinary catalytic activity towards the CO2 cycloaddition under mild conditions. Using this catalyst and TBAB, the highest TON (666 667) and TOF (52 713 h−1) were achieved compared to previously reported cobalt catalysts.
R. Chowdhury, I. A. Bhat, S. K. Sachan and G. Anantharaman, Dalton Trans., 2024, 53, 17157 DOI: 10.1039/D4DT02767A
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