A comparative study of moisture adsorption on GO, MOF-5, and GO/MOF-5 composite for applications in atmospheric water harvesting

Abstract

Water scarcity is an alarming situation across the globe. Several methods have been reported in the literature to minimize the water shortage problem. Sorbent-based atmospheric water harvesting (SBAWH) is considered an energy-efficient, low-cost strategy, and sustainable approach. In the present study, the synthesis of graphene oxide (GO) was carried out using a modified Hummers' method, while the synthesis of MOF-5 and a GO/MOF-5 composite was carried out using a solvothermal approach. The synthesized materials were characterized by X-ray diffraction analysis (XRD), scanning electron microscopy (SEM), and Fourier transform infrared spectroscopy (FTIR). The phase composition and crystallinity of all synthesized samples were confirmed by XRD analysis. SEM analysis provided information about the surface morphology of all synthesized samples. The adsorption of water vapors on surfaces of GO, MOF-5, and the GO/MOF-5 composite was evaluated by FTIR analysis. The negative charge was explored by the PZC technique on the surface of all synthesized materials. The water adsorption characteristics of GO, MOF-5, and the GO/MOF-5 composite were evaluated using an atmospheric water harvesting (AWH) plant. The maximum adsorption capacity of 542 mg g⁻¹ was achieved by the MOF at 55% RH (relative humidity), while a low adsorption capacity of the MOF was observed at higher humidity values. This problem was overcome by making a GO/MOF-5 composite. GO imparts structural stability to the MOF-5 structure at higher humidity values. The maximum adsorption capacity of 1137 mg g⁻¹ was achieved by the GO/MOF-5 composite at 75% RH. Several isotherm models, such as Langmuir, Freundlich, and Temkin, were applied to confirm the single-site occupation by water molecules and chemisorption behavior. Several thermodynamic properties were calculated, including isosteric heat (Q_st), Gibbs free energy (ΔG), and sorption entropy (ΔS). The overall thermodynamics study confirms that the adsorption process is spontaneous and exothermic. In addition, second-order kinetics confirms that all synthesized material shows chemisorption behavior.