Issue 24, 2024

Polyoxometalate-mediated syntheses of three structurally new silver clusters

Abstract

Three structurally new polyoxometalate-templated silver clusters, homometallic [(SiW9O34)@Ag24(iPrS)11(DPPP)6Cl]2(SiW12O40) (Ag24), heterometallic [(SiW9O34)@Ag22Cu(iPrS)11(DPPP)6Cl](SbF6)2 (Ag22Cu) and {Ag16(iPrS)6(DPPP)8(CH3COO)4[Co4(OH)3(H2O)SiW9O33]2}·(CH3CN)4 (Ag16Co8) (iPrS = isopropanethiolate, DPPP = 1,3-bis(diphenylphosphino)propane, SbF6 = hexafluoroantimonate) have been successfully synthesized using a facile solvothermal approach. The introduction of copper and cobalt ions can induce obvious changes in the molecular configuration of the obtained clusters, leading to distinct temperature-dependent photoluminescence and photothermal conversion properties.

Graphical abstract: Polyoxometalate-mediated syntheses of three structurally new silver clusters

Supplementary files

Article information

Article type
Communication
Submitted
09 May 2024
Accepted
25 May 2024
First published
27 May 2024

Nanoscale, 2024,16, 11518-11523

Polyoxometalate-mediated syntheses of three structurally new silver clusters

J. Zhang, Y. Dong, L. Deng, M. Chi, Y. Feng, M. Zhao, H. Lv and G. Yang, Nanoscale, 2024, 16, 11518 DOI: 10.1039/D4NR02016B

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