Characteristics and catalytic behavior of Ru–Sn bimetallic catalysts for TMCB hydrogenation to CBDO

Abstract

A series of Ru–Sn/γ-Al₂O₃ catalysts were prepared by the immersion method for tetramethylcyclobutane-1,3-dione (TMCB) hydrogenation to prepare 2,2,4,4-tetramethyl-1,3-cyclobutanediol (CBDO). The effect of the preparation method and reaction technology on TMCB hydrogenation activity was discussed. The catalysts were analyzed by means of XRD, BET, H₂-TPR, XPS, scanning electron microscopy (SEM), and transmission electron microscopy (TEM), and it was found that the synthesized Ru was distributed on the surface of the carrier in the form of nanoparticles, showing a good catalytic effect. The results showed that when Ru loading was fixed at 5%, Sn was used as an auxiliary agent, and Ru/Sn = 1 : 1 as the catalyst, the reaction conditions were 120 °C, 4 MPa, and 1 h, and the catalytic hydrogenation effect of TMCB on CBDO was the best. The selectivity was as high as 73.5%, and the cis–trans ratio was 1.11. It may be the strong interaction between Ru and Sn under this ratio condition, which leads to the largest number of nano-active centers of elemental Ru. Finally, the reaction mechanism of TMCB hydrogenation to CBDO is discussed.