Shear layers and plugs in the capillary flow of wormlike micellar gels

Abstract

Wormlike micellar solutions formed by long-chained zwitterionic surfactants show gel-like rheology at room temperature and have recently been found to exhibit other complex and interesting rheological features. We study the dynamics of these wormlike micellar gels in a pipe-flow scenario using particle imaging and tracking velocimetry and report the existence of plug flows with strong wall slip and non-parabolic velocity profiles for different surfactant concentrations and imposed flow rates. We rationalize these results as features of a developing transient flow of a viscoelastic solution in space and time. We show that evolution of shear layers is governed by intermittent flows, asymmetric velocity profiles and flow induced heterogeneity. Our experiments shed light on the transient fluid dynamics of wormlike micelles in simple geometries and highlight the complexity of flows involving wormlike micellar gels and similar soft matter systems in canonical flows.