Two-step seed swelling polymerization to prepare poly(glycidyl methacrylate-divinylbenzene) microspheres and their sulfonation for chromatographic separation of rare earth elements

Chen Shen; Yuqing Wei; Shuaishuai Wang; Hongwei Zhao; Qifang He; Hongdeng Qiu

doi:10.1039/D5AN00388A

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Two-step seed swelling polymerization to prepare poly(glycidyl methacrylate-divinylbenzene) microspheres and their sulfonation for chromatographic separation of rare earth elements†

Chen Shen,^ab Yuqing Wei,^ab Shuaishuai Wang,^ab Hongwei Zhao,^a Qifang He^a and Hongdeng Qiu

*^abc

Author affiliations

* Corresponding authors

^a Key Laboratory of Rare Earths, Ganjiang Innovation Academy, Chinese Academy of Sciences, Ganzhou 341119, China
E-mail: hdqiu@gia.cas.cn

^b School of Rare Earths, University of Science and Technology of China, Hefei 230026, China

^c Research Center for Natural Medicine and Chemical Metrology, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China

Abstract

A two-step seed swelling polymerization method was used to successfully synthesize monodisperse porous poly(glycidyl methacrylate-divinylbenzene) (PGMA-DVB) microspheres, which can be sulfonated and then used as new cation-exchange stationary phases for the separation of rare earth elements (REEs), demonstrating high resolution, stability, and selective separation of the REEs.

This article is part of the themed collection: 150th Anniversary Collection: Separation Science

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DOI: https://doi.org/10.1039/D5AN00388A
Article type: Communication
Submitted: 03 Apr 2025
Accepted: 28 May 2025
First published: 28 May 2025

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Analyst, 2025,150, 2776-2781

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Two-step seed swelling polymerization to prepare poly(glycidyl methacrylate-divinylbenzene) microspheres and their sulfonation for chromatographic separation of rare earth elements

C. Shen, Y. Wei, S. Wang, H. Zhao, Q. He and H. Qiu, Analyst, 2025, 150, 2776 DOI: 10.1039/D5AN00388A

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Two-step seed swelling polymerization to prepare poly(glycidyl methacrylate-divinylbenzene) microspheres and their sulfonation for chromatographic separation of rare earth elements†

Abstract

Supplementary files

Transparent peer review

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Two-step seed swelling polymerization to prepare poly(glycidyl methacrylate-divinylbenzene) microspheres and their sulfonation for chromatographic separation of rare earth elements

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