Sustainable upgrading of biomass: a thermodynamic approach to fine-tuning product selectivity for glycerol oxidation

Andrés F. Pérez-Torres; Heejung Kong; Fatwa F. Abdi; Roel van de Krol; Marco Favaro

doi:10.1039/D4CC04967E

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Sustainable upgrading of biomass: a thermodynamic approach to fine-tuning product selectivity for glycerol oxidation†

Andrés F. Pérez-Torres,*^ab Heejung Kong,

^ab Fatwa F. Abdi,

^c Roel van de Krol

^ab and Marco Favaro

*^a

Author affiliations

* Corresponding authors

^a Institute for Solar Fuels, Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, Hahn-Meitner-Platz 1, 14109 Berlin, Germany
E-mail: andres.perez_torres@helmholtz-berlin.de, marco.favaro@helmholtz-berlin.de

^b Institut für Chemie, Technische Universität Berlin, Straße des 17. Juni 124, 10623 Berlin, Germany

^c School of Energy and Environment, City University of Hong Kong, 83 Tat Chee Avenue, Kowloon, Hong Kong SAR, China

Abstract

Calculated thermodynamic properties for the electrochemical glycerol oxidation at different temperatures and potentials indicate that external applied bias has a more significant influence on reaction selectivity than temperature.

This article is part of the themed collection: Chemistry for a Sustainable World – Celebrating Our Community Tackling Global Challenges

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DOI: https://doi.org/10.1039/D4CC04967E
Article type: Communication
Submitted: 24 Sep 2024
Accepted: 30 Dec 2024
First published: 06 Jan 2025
This article is Open Access

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Chem. Commun., 2025,61, 2083-2086

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Sustainable upgrading of biomass: a thermodynamic approach to fine-tuning product selectivity for glycerol oxidation

A. F. Pérez-Torres, H. Kong, F. F. Abdi, R. van de Krol and M. Favaro, Chem. Commun., 2025, 61, 2083 DOI: 10.1039/D4CC04967E

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Chemical Communications

Sustainable upgrading of biomass: a thermodynamic approach to fine-tuning product selectivity for glycerol oxidation†

Abstract

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Sustainable upgrading of biomass: a thermodynamic approach to fine-tuning product selectivity for glycerol oxidation

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