Flow electrochemical oxidation of N-nitrosamines to N-nitramines

Abstract

N-nitro groups are a key functionality found in most energetic compounds. Conventional synthetic routes require the use of harsh reagents, such as fuming nitric acid. As an alternative, a biphasic electrochemical flow synthesis of N-nitramines from the oxidation of N-nitrosamines using molecular oxygen has been developed, proceeding via paired electrolysis.