Barkhausen noise in the columnar hexagonal organic ferroelectric BTA

Abstract

Upon a polarization reversal within a ferroelectric material, one stable state changes into another, which is typically described by a progression of switching events of smaller fractions of the material. These events give rise to crackling or Barkhausen noise and follow a characteristic distribution in their sizes. Barkhausen noise has been studied to better understand the switching processes of ferroelectrics and has been applied for inorganic ferroelectric materials and perovskites. In this work, we present results from kinetic Monte Carlo simulations investigating the switching process of the small organic molecular ferroelectric benzene-1,3,5-tricarboxamides (BTAs). For temperatures below 175 K and sufficiently strong structural disorder, the system exhibits self-organized critical behavior; for higher temperatures, a creep regime is entered. Our extracted power-law exponents are smaller than those typically measured in inorganic crystals and ceramics, which indicates that in the more disordered material BTA larger spanning avalanches are possible. The system was experimentally investigated with a high-sensitivity setup. No Barkhausen noise was observed, which is consistent with the simulated event sizes, lying several orders beneath the noise threshold of the experimental setup. This finding corroborates the notion that switching in BTA progresses along the 1D columns in the hexagonal liquid crystal lattice, with little coupling between the columns that could give rise to larger lateral avalanches.