From the journal:

Molecular Systems Design & Engineering

Construction of an organic cage-based porous ionic liquid using an aminal tying strategy

Aiting Kai,   Austin Mroz,   Kim E. Jelfs,   Andrew Cooper,   Marc Little  and  Rebecca L Greenaway  

Abstract

An aminal tying method was applied to post-synthetically modify a flexible organic cage, RCC1, to construct a porous ionic liquid (PIL). The resulting PIL, [RCC1-IM][NTf2]6, displayed melting behaviour below 100 °C, a transition to a glass phase on melt-quenching, CO2 uptake, and its permanent porosity was confirmed using molecular dynamic simulations.

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DOI
https://doi.org/10.1039/D5ME00004A
Article type
Paper
Submitted
14 Jan 2025
Accepted
01 Apr 2025
First published
02 Apr 2025
This article is Open Access
Creative Commons BY license

Mol. Syst. Des. Eng., 2025, Accepted Manuscript

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Construction of an organic cage-based porous ionic liquid using an aminal tying strategy

A. Kai, A. Mroz, K. E. Jelfs, A. Cooper, M. Little and R. L. Greenaway, Mol. Syst. Des. Eng., 2025, Accepted Manuscript , DOI: 10.1039/D5ME00004A

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